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Formation mechanism of nanocrystalline yttrium orthoferrite under heat treatment of the coprecipitated hydroxides
Authors:V I Popkov  O V Almjasheva  M P Schmidt  V V Gusarov
Institution:1.St. Petersburg State Technological Institute (Technical University),St. Petersburg,Russia
Abstract:Formation of nanocrystalline yttrium orthoferrite of ~30 nm average crystallite size from coprecipitated iron(III) and yttrium hydroxides was studied by thermo-X-ray diffractometry and simultaneous thermal analysis over 25–900°C temperature range. A mechanism of physicochemical transformations leading to the formation of YFeO3 nanoparticles was suggested.
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