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Nonadiabatic Corrections To The Vibrational Energies Of The Hydrogen Molecule
Authors:T Orlikowski  L Wolniewicz
Institution:Institute of Physics, N. Copernicus University, 87-100 Torun, Poland
Abstract:The nonadiabatic corrections to the vibrational levels of H2 and D2 are evaluated for the X1+g state by taking into account the coupling with the E, F1+g electronic state. The computed corrections diminish the existing discrepancy between the experimental and theoretical vibrational quanta by about 20%.
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