Fast formation of aromatic cations in cyclohexane observed by pulse radiolysis |
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| Authors: | O. Brede W. Helmstreit R. Mehnert |
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| Affiliation: | Zentralinstitut für Isotopen- und Strahlenforschung der Akademie der Wissenschaften der DDR, 705 Leipzig, GDR |
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| Abstract: | The fast formation of cations of benzophenone, biphenyl, naphthalene, anthracene and phenanthrene in liquid cyclohexane was studied by nanosecond pulse radiolysis. Rate constants between 2.3 × 1010 M?1 s?1 (for naphthalene) and not below 2.5 × 1012 M?1 s?1 (for benzophenone) were derived and compared with the corresponding rate constants for anion formation. |
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