Selection rule in free radical reactions |
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| Authors: | Kizashi Yamaguchi |
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| Affiliation: | Department of Chemistry, Faculty of Engineering Science, Osaka University, Toyonaka, Osaka, Japan |
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| Abstract: | The insertion and abstraction reactions are investigated on the basis of the Heisenberg model. These reactions are characterized as spin-symmetry forbidden and allowed reactions, respectively. It is pointed out that free radical reactions occur readily when there is no spin degeneracy in the course of these reactions. The rule obtained is discussed in relation to the orbital symmetry conservation rule for concerted reactions. |
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