Fine structure in Rydberg states of the H2 molecule |
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| Authors: | A.Norman Jette Terry A. Miller |
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| Affiliation: | Applied Physics Laboratory, The Johns Hopkins University, Silver Spring, Maryland 20910, USA;Bell Laboratories, Murray Hill, New Jersey 07974, USA |
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| Abstract: | The electron spin—nuclear rotation interaction is considered for the np 3Πu Rydberg series of the H2 molecule for which much experimental data is available. Earlier formulations of this interaction are reconciled and consistent formulae for both the heteronuclear and homonuclear case are presented. Theoretical calculations of various contributions are given and compared to experimental results. Excellent agreement between calculated and experimental values is obtained for the np Rydberg series of H2 including H2+. |
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