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Electron spin polarization in the photoexcited triplet state of porphyrins
Authors:H Levanon  A Wolberg
Institution:Department of Physical Chemistry, The Hebrew University, Jerusalem, Israel;Nuclear Research Center - Negev. Beer Sheva, Israel
Abstract:Electron spin polarization in the photoexcited triplet state of tetraphenyl porphyrin was detected at 100°K using EPR technique. The zero field splitting parameters |D| and |E| the free base porphyrin were found to be 0.0369 ± 0.0005 and 0.0082 ± 0.0005 cm?1, respectively.
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