The preparation of cobalt complexes containing simple sulphur-nitrogen ligands,S2N2H− and S3N−, from S4N4O2 |
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| Authors: | John C. Burgess Z. Erhan Tatar J. Derek Woollins |
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| Affiliation: | (1) Department of Chemistry, Imperial College of Science and Technology, SW7 2AY London, UK |
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| Abstract: | Summary Reactions of Group VIII metal halides [CoCl2, NiCl2, K2PdCl4, PdCl2(PhCN)2 and PtCl2] with tetrasulphurtetranitrogendioxide, S4N4O2, have been investigated. The cobalt reaction yields Co(S2N2H)2, Co(S2N2H)(S3N) and Co(S3N)2. The usefulness of metal centres for trapping reactive sulphur-nitrogen centres is discussed. |
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