The two spin states of an end-on copper(II)-superoxide mimic |
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| Authors: | Askari Mohammad S Girard Brigitte Murugesu Muralee Ottenwaelder Xavier |
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| Institution: | Department of Chemistry and Biochemistry, Concordia University, 7141 Sherbrooke W, Montreal, QC H4B 1R6, Canada. |
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| Abstract: | The reaction of nitrosobenzene with copper(I) complexes of a tetradentate ligand led to two novel species that are best described as copper(II) complexes of an O-bonded nitrosobenzyl radical anion, in either the singlet or the triplet spin-state. Both states were characterized by crystal structures, magnetic measurements and DFT calculations. |
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