The influence of the mercury and thallium atoms in organomercury and organothallium nitroxyl radicals on their reactivity |
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| Authors: | A. D. Malievskii S. V. Koroteev A. B. Shapiro |
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| Affiliation: | (1) N.N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 117977 Moscow, Russian Federation |
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| Abstract: | An increase is found in the reactivity of organomercury and organothallium nitroxyl mono- and biradicals of the imidazoline type in comparison with the analogous compounds without organometallic fragments. This is explained by the formation of coordination bonds N Hg, NTl, and NOHg.Translated fromIzvestiya Akademii Nauk, Seriya Khimicheskaya, No. 1, pp. 224–226, January, 1993. |
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| Keywords: | kinetics organomercury nitroxyls organothallium nitroxyls coordination bond hydrazobenzene reduction rate constant |
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