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新型胺基壳聚糖树脂的合成及其对胆红素吸附性能的研究
引用本文:徐慧,肖玲,李洁,杜予民.新型胺基壳聚糖树脂的合成及其对胆红素吸附性能的研究[J].离子交换与吸附,2003,19(6):489-495.
作者姓名:徐慧  肖玲  李洁  杜予民
作者单位:武汉大学环境科学系,武汉,430072
基金项目:国家自然科学基金 (29977014)
摘    要:以壳聚糖为原料,经羟丙基氯化、胺基化,制备了一种新型胺基壳聚糖树脂,研究了该树脂对胆红素的吸附性能。结果表明:胺基壳聚糖树脂的胺基含量比壳聚糖高,该树脂对游离胆红素的吸附在3h基本达到平衡,吸附量随着胺基含量增加而增加,树脂的吸附性能受温度、离子强度影响。胺基壳聚糖树脂对血清白蛋白结合胆红素的吸附量大于壳聚糖,但低于对游离胆红素的吸附。

关 键 词:壳聚糖  胆红素  吸附性能  胺基壳聚糖树脂  合成  肝病
文章编号:1001-5493(2003)06-0489-07
修稿时间:2003年6月4日

STUDY ON ADSORPTION PROPERTIES FOR BILIRUBIN OF NOVEL AMINATED CHITOSAN RESIN
XU Hui,XIAO Ling,LI Jie,DU Yumin.STUDY ON ADSORPTION PROPERTIES FOR BILIRUBIN OF NOVEL AMINATED CHITOSAN RESIN[J].Ion Exchange and Adsorption,2003,19(6):489-495.
Authors:XU Hui  XIAO Ling  LI Jie  DU Yumin
Institution:XU Hui XIAO Ling LI Jie DU Yumin Department of Environmental Science,Wuhan University,Wuhan 430072,China
Abstract:A novel aminated chitosan resin was prepared by chitosan Schiff base intermediate, through hydroxylpropyl-chloridization and amination. The adsorption properties of the aminated chitosan resin were investigated. The results showed that the amine-group content for the novel aminated chitosan resin was improved compared with chitosan. The adsorption capacity for dissociated bilirubin was increased with the increment of the amine-group content and related to the adsorption temperature and the ion strength. The adsorption capacity of the resin for combined bilirubin is stronger than that of chitosan.
Keywords:Chitosan  Bilirubin  Adsorption  Aminated chitosan resin  
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