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Reactivity of (2,4-cycloheptadiene-1,6-dione)Fe(CO)3: synthesis of hinokitiol and (7,8-diphenylheptatriafulvalene-1,6-quinone)Fe(CO)3
Authors:Noboru Morita  Mitsuhiro Kurita  Koichi Saito  Maki Kinjo  Shunji Ito  Toyonobu Asao  Masako Ueno  Toshio Sato  Akio Tajiri  Masafumi Yasunami
Affiliation:aDepartment of Chemistry, Graduate School of Science, Tohoku University, Aramaki Aza Aoba, Aobaku, Sendai 980-8578, Japan;bDepartment of Materials Science, Faculty of Science and Technology, Hirosaki University, Hirosaki 036-8224, Japan;cCollege of Engineering, Nihon University, Koriyama 963-1165, Japan
Abstract:The reactivities of tricarbonyl(2,4-cycloheptadiene-1,6-dione)iron toward several kinds of nucleophiles and electrophiles were investigated. As a result, it was found that tricarbonyl(2,4-cycloheptadiene-1,6-dione)iron has several reaction sites and undergoes several types of reactions. A new synthetic route to hinokitiol and tricarbonyl-(7,8-diphenylheptariafulvalene-1,6-quinone)iron from (2,4-cycloheptadiene-1,6-dione)iron was explored.
Keywords:Hinokitiol   Nucleophile   Iron   Cycloheptadiene   Fulvalene
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