| 新型膨胀阻燃剂的合成及其在涤纶织物中的应用 |
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| 引用本文： | 丁佩佩,张灯青,葛凤燕,蔡再生.新型膨胀阻燃剂的合成及其在涤纶织物中的应用[J].合成化学,2010,18(1). |
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| 作者姓名： | 丁佩佩 张灯青 葛凤燕 蔡再生 |
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| 作者单位： | 东华大学,化学化工与生物工程学院,上海,201620 |
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| 基金项目： | 教育部重点资助项目，上海市经委上海市引进技术的吸收与创新资助项目 |
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| 摘 要： | 氧氯化磷与季戊四醇反应制得双氯螺磷(2);2与三乙醇胺反应合成了新聚合物1,其结构与性能经1H NMR,IR,TG和SEM表征。研究结果表明,1自身具有很好的成炭性,对涤纶织物具有很好的阻燃效果,扩展了涤纶的分解温度范围;通过SEM对经1整理的织物残炭形貌进行分析,证实1是膨胀型的阻燃剂。
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| 关 键 词： | 膨胀型阻燃剂 涤纶 热稳定性 残炭 合成 |
Synthesis of a Novel Intumescent Flame Retardant and Its Application in Polyester Fabric |
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| DING Pei-pei,ZHANG Deng-qing,GE Feng-yan,CAI Zai-sheng.Synthesis of a Novel Intumescent Flame Retardant and Its Application in Polyester Fabric[J].Chinese Journal of Synthetic Chemistry,2010,18(1). |
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| Authors: | DING Pei-pei ZHANG Deng-qing GE Feng-yan CAI Zai-sheng |
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| Abstract: | Dichloro phosphorspirol(2) was synthesized from phosphorus oxychloride and pentaerythritol,then reacted with triethanolamine to obtain a new polymer(1).The structure and flame retardant property of 1 were characterized by ~1H NMR,IR,TG and SEM.The results showed that 1 exhibited good char forming performance itself and flame retardant property on polyester fabrics,also promoted the polyester char-forming.1 reduced the initial degradation temperature,and extended the decomposition temperature range of polyester.The morphology analysis of residue carbon from SEM confirmed intumescent flame retardant identity of 1. |
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| Keywords: | intumescent flame retardant polyester thermal stability residue carbon synthesis |
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