| 含三苯胺结构的可溶性聚甲亚胺的合成 |
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| 引用本文： | 朱明,刘晓,刘佰军,姜振华.含三苯胺结构的可溶性聚甲亚胺的合成[J].高等学校化学学报,2011,32(12):2714-2716. |
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| 作者姓名： | 朱明 刘晓 刘佰军 姜振华 |
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| 作者单位： | 吉林大学麦克德尔米德实验室, 长春 130012 |
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| 基金项目： | 吉林省科技发展计划，中央直属高校基本科研业务费 |
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| 摘 要： | 本文设计并合成了含有三芳胺结构的二胺单体, 分别与3种商品化二醛单体于室温进行聚合, 制备出新型的可用于空穴传输材料的可溶性聚甲亚胺材料.
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| 关 键 词： | 聚甲亚胺 可溶性 空穴传输材料 |
| 收稿时间： | 2011-07-27 |
Synthesis of Soluble Polyazomethines Containing Triarylamine Units |
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| ZHU Ming,LIU Xiao,LIU Bai-Jun,JIANG Zhen-Hua.Synthesis of Soluble Polyazomethines Containing Triarylamine Units[J].Chemical Research In Chinese Universities,2011,32(12):2714-2716. |
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| Authors: | ZHU Ming LIU Xiao LIU Bai-Jun JIANG Zhen-Hua |
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| Institution: | Alan G. MacDiarmid Institute, Jilin University, Changchun 130012, China |
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| Abstract: | Based on a new diamine monmer, three polyazomethines containing triaylamine units were readily prepared through polycondensation reactions at room temperature. These polymers exhibit high Tg values(188-220 ℃), good thermal stability and improved solubility. The charge carrier mobility of the thiophene-containing polyazomethine could reach 1.94×10-4 cm2/(V?s). |
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| Keywords: | Polyazomethine Solubility Hole transport material Triarylamine |
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