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In search of fullerene-based superacids: synthesis, X-ray structure, and DFT study of C60(C2F5)(5)H
Authors:Kuvychko Igor V  Shustova Natalia B  Avdoshenko Stanislav M  Popov Alexey A  Strauss Steven H  Boltalina Olga V
Affiliation:Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA.
Abstract:Simply super! The perfluoroalkylfullerene C(60)(C(2)F(5))(5) H is the first structurally characterized perfluoroalkylated fullerene-based acid and is also predicted to be the first gas-phase fullerene-based superacid.
Keywords:acidity  density functional calculations  fullerenes  perfluoroalkylation  superacidic systems
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