Non-equilibrium ion-(polar) molecule reaction rate coefficients |
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| Authors: | R. Schmidt R. Schuster W. Stiller |
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| Affiliation: | (1) Central Institute for Isotope and Radiation Research, Academy of Sciences of the GDR, Permoserstr. 15, DDR-7050 Leipzig |
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| Abstract: | Using the Fokker-Planck version of an approximate Boltzmann equation for the ion (translational) energy distribution function fI we have calculated the deviation,  k, of the non-equilibrium ion-(polar)molecule reaction rate coefficient k (based) on fI from its equilibrium value k(0). The  D (dipole moment)-dependence of the reaction cross section applied leads to a corresponding dependence of k on D.
                 -          ,  k  - ( fI) k(0).  k D.
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