Template-Directed Synthesis of Macroheterocycles by Ring-Closing Metathesis of Olefin-Substituted Pyridines in the Coordination Sphere of a Triplatinum Complex |
| |
| Authors: | Chuchuryukin A. V. Dijkstra H. P. Suijkerbuijk B. M. J. M. Klein Gebbink R. J. M. van Klink G. P. M. Mills A. M. Spek A. L. van Koten G. |
| |
| Affiliation: | (1) Debye Institute, Department of Metal-Mediated Synthesis, Utrecht University, Utrecht, The Netherlands;(2) Bijvoet Center for Biomolecular Research, Department of Crystal and Structural Chemistry, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands |
| |
| Abstract: | Mono- and tris-3,5- and 2,6-pyridinediyl-containing macroheterocycles were synthesized by metathesis of olefin-substituted pyridines in the coordination sphere of mono- and tris-platinum complexes, respectively. Tris(2,6-pyridinediyl)-containing macroheterocycles were hydrogenated over palladium catalyst. The hydrogenated macrocycle was used as ligand for the triplatinum template. The structure of the resulting complex was established by X-ray analysis. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
