Thermal analysis of cobalt(II), nickel(II), copper(II) and zinc(II) bis (3,5-dimethyl-1-pyrazolyl)dihydroborates |
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Authors: | UBiader Ceipidor M Tomassetti F Bonati R Curini G Dascenzo |
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Institution: | Istituto di Chimica Analitica, Università degli Studi di Roma, Rome Italy;Dipartimento di Scienze Chimiche, Università degli Studi di Camerino, Camerino Italy |
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Abstract: | Complexes of general formula MH2B(Me2pz)2]2, where M = Co(II), Ni(II), Cu(II), and Zn(II)] are characterized by thermal analysis and complementary techniques. Mixtures of boron and metal oxides are found as final residues. Relative thermal stability (Ni > Cu > Co = Zn) and thermal behaviour are discussed. Melting and sublimation data are compared with those referred to in the literature. |
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