Thermodynamic properties of simple alkenes |
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Authors: | Jing Chao Kenneth R. Hall Jian-min Yao |
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Affiliation: | thermodynamics Research Center, Texas A&M University, College Station, TX 77843 U.S.A.;Nanjing Institute of Chemical Technology, Nanjing, Jiangsu The People''s Republic of China |
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Abstract: | Employing low temperature thermal measurements, heat capacities (Cs) in the crystal and liquid states, and phase transition data, Tm and ΔHm, the condensed phase thermodynamic properties, (Gs -H°0)/T, Hs -H°0, Ss and Cs, in the temperature range 0–360 K were evaluated for the following eleven alkenes: ethylene, propylene, 1-butene, cis-2-butene, trans-2-butene, 1-pentene, cis-2-pentene, trans-2-pentene, 2-methyl-1-butene, 3-methyl-1-butene and 2-methyl-2-butene. The sources of experimental data, methods of evaluation, and the calculated results are described in detail. |
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