Synthesis,stereochemistry, and isomeric transformations of 4-aryl-5-aroyl-2-methylthio-2-imidazolines |
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| Authors: | V A Konovalov O N Bubel' I G Tishchenko |
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| Institution: | (1) A. N. Sevchenko Scientific-Research Institute of Applied Physical Problems, 220065 Minsk |
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| Abstract: | The corresponding 4-aryl-5-aroyl-2-methylthio-2-imidazolines were obtained by the reaction of complexes of cis- and trans-3-aroylaziridines and boron trifluoride with methyl thiocyanate. It is shown on the basis of spectral data that the aziridine ring is opened regiospecifically at the C(2) atom and stereospecifically with inversion of the configuration.Deceased.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1484–1488, November, 1988. |
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