C-H and C-C bond activation of primary amines through dehydrogenation and transimination |
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| Authors: | Jun C H Chung K Y Hong J B |
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| Institution: | Department of Chemistry, Yonsei University, Seoul 120-749, Korea. junch@yonsei.ac.kr |
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| Abstract: | structure: see text]. Dehydrogenation and subsequent transimination of primary amines offer a new pathway for C-H bond activation, ortho-alkylation, and C-C bond activation to afford a variety of ketones in the reaction of 1-alkene by a cocatalyt system of Rh(I) and 2-amino-3-picoline. |
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