The role played by some factors of intramolecular interaction in nonradiative deactivation of the lowest triplet state of octachlorodibenzo-p-dioxin |
| |
| Authors: | E A Gastilovich V G Klimenko L V Volkova R N Nurmukhametov |
| |
| Institution: | 1. Karpov Institute of Physical Chemistry State Scientific Center of the Russian Federation, Moscow, 105064, Russia
2. MAMI Moscow State Technical University, Moscow, 107023, Russia
|
| |
| Abstract: | We have studied how intramolecular interactions, such as vibronically induced spin-orbit (VISO) and nonadiabatic interactions, which are governed by different structural elements of the octachlorodibenzo-p-dioxin (OCDD) molecule, affect the deactivation of its lowest triplet state. In the nonadiabatic approximation, taking into account out-of-plane vibrational modes as promoting ones, we have estimated the values of rate constant K dg s of the nonradiative energy deactivation of in-plane triplet sublevels (s = z, y) of the triplet state of the OCDD molecule. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
