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A Passerini/Tsuji-Trost access to dienamide derivatives |
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| Authors: | Sihem Dali Youcef Mansour Dolè Kerim Hocine Ilitki Laurent El Kaïm |
| Institution: | 1. Laboratoire de Synthèse Organique, CNRS, Ecole Polytechnique, ENSTA ParisTech-UMR 7652, Université Paris-Saclay, 828 Bd des Maréchaux, 91128 Palaiseau, France;2. Laboratoire de Chimie et d’Electrochimie, Département de Chimie, Université des sciences et de la technologie d''Oran. Mohamed Boudiaf USTO-MB, BP1505,El M''nouar 31000 Oran, Algeria |
| Abstract: | The Passerini reaction of α, β-unsaturated aldehydes affords allylic acetates which may be involved in Tsuji-Trost elimations towards conjugated dienamides. The interest of these 2,4-dienamides has been demonstrated in several TiCl4 triggered Diels-Alder reactions with N-phenylmaleimide. |
| Keywords: | Passerini Tsuji-Trost 1 3-Diene Diels-Alder Isocyanide |
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