Total syntheses via cyclopropanols |
| |
| Authors: | Xinpei Cai Weida Liang Mingji Dai |
| |
| Affiliation: | Department of Chemistry, Center for Cancer Research and Institute of Drug Discovery, Purdue University, West Lafayette, IN, 47907, USA |
| |
| Abstract: | Cyclopropanols are readily available via the Kulinkovich cyclopropanation, the Simmons-Smith reaction, and other synthetic methods. Due to their intrinsic ring stains, cyclopropanols and their derivatives are highly reactive and can be converted to different structural scaffolds which are frequently found in many natural products. In this review, we highlight the applications of various cyclopropanol ring opening/expansion/fragmentation reactions in the total syntheses of natural products. |
| |
| Keywords: | Total synthesis Cyclopropanol Natural product Ring opening Metal catalysis |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
