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Copper p-toluenesulfonate/acetic acid: a recyclable synergistic catalytic system for the tetrahydropyranylation of alcohols and phenols
Authors:Min Wang  Zhi-Guo Song  Heng Jiang  Hong Gong
Affiliation:(1) College of Chemistry and Chemical Engineering, Bohai University, Jinzhou, China;(2) Center for Science and Technology Experiment, Bohai University, Jinzhou, China;(3) Liaoning Shihua University, Fushun, China
Abstract:Copper p-toluenesulfonate/acetic acid was found to be an efficient, chemoselective synergistic catalytic system, with catalyst loading as low as 0.3 mol% leading to clean, high-yielding tetrahydropyranylation of a variety of alcohols and phenols. By simple phase-separation, copper p-toluenesulfonate can be easily recovered and reused for several times without deterioration in catalytic activity. Correspondence: Min Wang, College of Chemistry and Chemical Engineering, Bohai University, Jinzhou, China.
Keywords:Tetrahydropyranylation   Alcohols and phenols   Synergistic catalysis   Chemoselectivity   Reusability.
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