Characteristics of molecular sorption on template containing mesoporous molecular sieves of type MCM-41 |
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Authors: | F. M. Bobonich A. S. Kovalenko Yu. G. Voloshina V. N. Solomakha A. S. Korchev A. P. Filippov V. G. Il'in |
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Affiliation: | (1) Department of Environmental Microbiology, UFZ, Helmholtz Centre for Environmental Research, Leipzig, Germany;(2) Department of Environmental Chemistry and Microbiology, The National Environmental Research Institute (NERI), Roskilde, Germany |
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Abstract: | Template containing materials of type MCM-41 have properties of microporous substances. On absorption into the micropores of such materials the dependence of the characteristic absorption energies on the molecular mass of the sorptive is extreme, and the specific absorption volume decreases with increased molar volume of the sorptive. A model is proposed to explain the peculiarities of the absorption properties of the template containing materials. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine 31 Prospekt Nauki, Kiev 252039, Ukraine. Translated from Teoreticheskaya i éksperimental'naya Khimiya, Vol. 35, No. 6, 367–372, November–December, 1999. |
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