Kinetics and mechanism of acetylene hydromethylation on organonickel catalysts |
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| Authors: | N P Trukhacheva and N F Noskova |
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| Institution: | (1) Institute of Organic Catalysis and Electrochemistry, 480100 Alma-Ata, USSR |
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| Abstract: | Kinetics of methane interaction with acetylene on Ziegler-Natta type organonickel catalysts has been studied. The reaction is first order with respect to methane. The kinetic isotope effect amounts to KCH
4/KCD
4=1.5 and KC
2H2,CH4,H2/KC
2D2,CD4,D2=2.0.
                         - .  - .    KCH
4/KCD
4, KC
2H2,CH4,H2/KC
2D2,CD4,D2 1,5; 2,0.  .
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| Keywords: | |
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