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Binding properties and self-assembly of C2v-symmetrical resorcin[4]arene tetrabenzoates
Authors:Svetlana V ShishkinaAndriy Tarnovskiy  Vladimir RozhkovOleg V Shishkin  Oleg LukinAlexander Shivanyuk
Institution:a STC “Institute for Single Crystals”, The National Academy of Science of Ukraine, 60 Lenin ave., 61001 Kharkiv, Ukraine
b The Institute of Organic Chemistry, The National Academy of Sciences of Ukraine, 5 Murmanska Str., 02660 Kiev 94, Ukraine
c The Institute of High Technologies, Kyiv National Taras Shevchenko University, 4 Glushkov st., Building 5, 03187 Kiev, Ukraine
d ChemBioCenter Kiev, National Taras Shevchenko University, 62 Volodymyrska str., 01033 Kiev, Ukraine
e Macrochem, 4 Lunacharsky Street, Floor 7, 02002 Kiev, Ukraine
f The Institute of Toxicology and Pharmacology, The National Academy of Medical Sciences, 14 Ejen Pottier Str, 03680 Kiev, Ukraine
Abstract:In the crystalline state two molecules of resorcin4]arene tetrabenzoates and four chloride anions form molecular wraps containing two Et3NH+ cations. The structure and composition of the wraps depend on the length of the alkyl chains at the narrow rim of the macrocycle. Resorcin4]arene tetrabenzoates interact with ammonium salts in CDCl3.
Keywords:Resorcinarenes  Hydrogen bonds  Self-assembly  X-ray crystallography
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