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Ionic motion in the defect pyrochlore NH4TaWO6
Authors:M.A. Butler  R.M. Biefeld
Affiliation:Physics Department, The University of British Columbia Vancouver, B.C., V6T 1W5, Canada
Abstract:Measurement of both spin-lattice and spin-spin relaxation time for protons in NH4TaWO6 suggest rapid ionic motion in this compound. Analysis of the data gives an activation energy of ~0.3 eV and an attempt frequency of ~1×1010 sec?1. The data is used to suggest a model for ionic motion which involves movement of individual protons rather than the NH4+ ion.
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