EPR of orthorhombic Gd3+-M+ complexes in SrF2 |
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Authors: | EJ Bijvank AG Zandbergen-Beishuizen HW den Hartog |
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Institution: | Solid State Physics Laboratory, 1 Melkweg, Groningen, The Netherlands |
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Abstract: | In this paper we report new results of EPR experiments on orthorhombic Gd3+-M+ complexes (M = Na, K, Rb and Ag) in SrF2. Special attention is payed to the second degree crystal field parameters B02 and B22 and a comparison with earlier results on corresponding complexes in CaF2 and BaF2 is made. We conclude that the main contributions to these crystal field parameters are of electrostatic nature. |
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