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Synthesis and Crystal Structures of the α and β Forms of Bis (salicylaldoxime) copper ( Ⅱ ) Complexes
作者姓名:WAN Jun 1  2  WANG Shi-ying2  WEN Yong-hong2  YE Su-juan2 OUYANG Ping-kan1 and ZHANG Shu-sheng 2 1. College of Life Science and Pharmaceutical Engineering  Nanjing University of Technology  Nanjing 210093  P. R. China   2. College of Chemistry and Molecular Engineering  Qingdao University of Science and Technology  Qingdao 266042  P. R. China
作者单位:WAN Jun 1,2,WANG Shi-ying2,WEN Yong-hong2,YE Su-juan2 OUYANG Ping-kan1 and ZHANG Shu-sheng 2 1. College of Life Science and Pharmaceutical Engineering,Nanjing University of Technology,Nanjing 210093,P. R. China; 2. College of Chemistry and Molecular Engineering,Qingdao University of Science and Technology,Qingdao 266042,P. R. China
基金项目:SupporredbytheProgramforNewCenturyExcellentTalentsinUniversities(No.NCET-04-0649)andtheNationalNaturalScienceFoundationofChina(Nos.20275020and20475030).
摘    要:IntroductionSalicylaldoxime can be used in chemically modi-fied glassy-carbon electrodes,and applied to the deter-mination of metals in water.It shows a very high recov-ery[1,2].Direct design of solid-state structures that en-compass frameworks such as grids,ladders,helicesand channels of a desired architecture is central to crys-tal engineering science[3,4].Each of the oxidationstates of copper displays a different stereochemistry,ofwhich Cu(Ⅱ)is the most representative example foritsd9elec…

关 键 词:合成 晶体结构 水杨醛肟 铜配合物 X射线衍射
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