CO hydration over catalysts prepared via supporting Fe3(CO)12 and (NEt4)2[Fe2Mn(CO)12] on oxide supports |
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| Authors: | V L Kuznetsov A F Danilyuk I E Kolosova and Yu I Yermakov |
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| Institution: | (1) Institute of Catalysis, Novosibirsk, USSR |
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| Abstract: | A comparison of the properties of iron-containing catalysts prepared through carbonyl clusters Fe3(CO)12 and (NEt4)2Fe2Mn(CO)12] and iron and manganese nitrates in CO hydration indicates that the addition of Mn incorporated in (NEt4)2Fe2Mn(CO)12] decreases the methane yield and increases the portion of higher hydrocarbons.
                   ,      Fe(CO)12 (NEt4)2Fe2Mn(CO)12]  ,  CO.  Mn (NEt4)2Fe2Mn(CO)12]     .
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