Enantioselective hydrogenation on heterogeneous metal catalysts |
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| Authors: | E I Klabunovskii A A Vedenyapin Yu S Airapetov and Ya D Fridman |
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| Institution: | (1) Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow, USSR |
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| Abstract: | The rate of formation of the excess of one enantiomeric product in the enantioselective hydrogenation of ethyl acetoacetate (EAA) and acetylacetone (acac) on a Raney copper catalyst modified with chiral aminoacids (AmA) correlates with the formation constants of the mixed complexes CU EAA AmA] and Cu acac AmA].
                           (  ) - () ,  ( )  Cu··] Cu··].
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