Interpretation of the absorption spectra of the hexaaquo cobalt(II) and hexammine cobalt(II) ions |
| |
| Authors: | I I Volchenskova K B Yatsimirskii |
| |
| Institution: | (1) Institute of General and Inorganic Chemistry, AS UkrSSR, Kiev |
| |
| Abstract: | The absorption spectra of the complex ions Co(H2O)6]2+ and Co(NH3)6]2+ in solution have been studied. The spectra were analyzed after breakdown of the bands into their Gaussian components by means of the formalism of a crystal field with irregular octahedral symmetry. It has been shown that interpretation of the spectra is possible only with allowance for spin-orbital coupling and orthorhombic distortion. The results obtained differ significantly from the published data. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
