Alkenylpyridine and alkenylamine complexes of palladium |
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| Authors: | Hayes Paul G. Stringer Sylvie A. M. Vogels Christopher M. Westcott Stephen A. |
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| Affiliation: | (1) Department of Chemistry, Mount Allison University, Sackville, NB, E4L 1G8, Canada |
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| Abstract: | Addition of alkenylamines and alkenylpyridines to trans-[PdCl2(coe)]2(1) (coe = C8H14) afforded complexes of the type trans-PdCl2L2 (where L is a nitrogen-containing ligand). Coordination of the alkenylamine or alkenylpyridine groups occurred primarily through the nitrogen atom in all cases. Addition of aminopropylvinylether (apve = H2NCH2CH2CH2OCH=CH2) to (1) gave trans-PdCl2(thmo)2(9) (thmo = tetrahydro-2-methyl-1,3-oxazine) via an intramolecular hydroamination. |
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