Rate constants for tsomerization of C6H5C(SC6H5)2 ĆH2 radicals to C6H5Ć(SC6H5)CH2SC6H5 radicals based on EPR data |
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| Authors: | R G Gasanov R G Petrova R Kh Freidlina |
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| Institution: | (1) A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Conclusions The parameters of the Arrhenius equation for the isomerization of PhC(SPh)2 H2 radicals to Ph(SPh)CH2. SPh radicals are in agreement with an intramolecular character of the rearrangement, with a 1,2-migration of the thiyl group. These parameters were calculated on the basis of the data that were obtained by the EPR method in the range 10–70°.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2596–2597, November, 1982. |
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