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Fluoride-promoted oxidation of Fischer alkoxy carbene complexes: stoichiometric and catalytic conditions |
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| Authors: | Barluenga José Andina Facundo Fernández-Rodríguez Manuel A García-García Patricia Merino Isabel Aguilar Enrique |
| Affiliation: | Instituto Universitario de Química Organometálica "Enrique Moles", Unidad Asociada al CSIC, Universidad de Oviedo, C/Julián Clavería, 8, 33006 Oviedo, Spain. barluenga@uniovi.es |
| Abstract: | The utility of fluoride anion as promoter of the oxidation of Fischer carbene complexes is presented. Two different and complementary methods that allow the fast and convenient preparation of carbene-derived esters in good yields have been developed using stoichiometric or catalytic quantities of fluoride ion. |
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