A New Hybrid Organic–Inorganic Membrane Based on Self-Organized Urea Macrocyclic Siloxane Material as Useful Facilitated Transport Device for Biological Solutes |
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| Authors: | N Hovnanian S Cerneaux P Dieudonné |
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| Institution: | 1. Institut Européen des Membranes de Montpellier, UMR 5635-CNRS 1919 route de Mende 34293 Montpellier, Cedex 5, France
2. Groupe de Dynamique des Phases Condensées, UMR 5581-CNRS Université Montpellier II, Place Eugène, Bataillon, 34095, Montpellier Cedex 5, France
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| Abstract: | A new organic-inorganic hybrid membrane was synthesized in which organic moieties presented a self-assembly of anionic and cationic complexing sites covalently bonded to a siloxane network. The effects of sol–gel parameters (hydrolysis ratio, catalyst and temperature) on the self-organization of the organic functions were studied. Transport experiments underlined the results of such ordering on the improvement of the solute permeability. |
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