Apparent molar heat capacities and volumes of aqueous electrolytes: CaCl2, Cd(NO3)2, CoCl2, Cu(ClO4)2, Mg(ClO4)2, and NiCl2 |
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Authors: | Jan J Spitzer Prem Paul Singh Keith G McCurdy Loren G Hepler |
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Institution: | (1) Department of Chemistry, University of Lethbridge, Lethbridge, Alberta, Canada;(2) Present address: Department of Chemistry, Punjab Agricultural University, Ludhiana, India |
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Abstract: | We have used a flow calorimeter and a flow densimeter for measurements leading to apparent molar heat capacities and apparent molar volumes of six 21 electrolytes in aqueous solution at 25°C. Results of these measurements have been used to derive apparent molar heat capacities and volumes at infinite dilution for all six electrolytes: CaCl2, Cd(NO3)2, CoCl2, Cu(ClO4)2, Mg(ClO4)2, and NiCl2. |
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Keywords: | Heat capacities of electrolytes volumes of electrolytes molar volumes aqueous solutions unsymmetrical electrolytes calcium cobalt and nickel chlorides cupric and magnesium perchlorates cadmium nitrate |
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