Novel,stereoselective tricyclization of a dienyne by titanium aryloxide centers |
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Authors: | Himes Richard A Fanwick Phillip E Rothwell Ian P |
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Institution: | Department of Chemistry, Purdue University, 1393 Brown Building, West Lafayette, IN 47907-1393, USA. |
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Abstract: | Titanium centers supported by aryloxide ligation mediate the tricyclization of a dienyne via intramolecular insertion of an olefin into the titanium-vinyl bond of a titanacyclopent-2-ene. |
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