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Novel,stereoselective tricyclization of a dienyne by titanium aryloxide centers
Authors:Himes Richard A  Fanwick Phillip E  Rothwell Ian P
Institution:Department of Chemistry, Purdue University, 1393 Brown Building, West Lafayette, IN 47907-1393, USA.
Abstract:Titanium centers supported by aryloxide ligation mediate the tricyclization of a dienyne via intramolecular insertion of an olefin into the titanium-vinyl bond of a titanacyclopent-2-ene.
Keywords:
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