Different adsorption behaviors of methane and carbon dioxide in the isotypic nanoporous metal terephthalates MIL-53 and MIL-47 |
| |
| Authors: | Bourrelly Sandrine Llewellyn Philip L Serre Christian Millange Franck Loiseau Thierry Férey Gérard |
| |
| Institution: | MADIREL, Université de Provence - CNRS UMR 6121, Centre de St Jér?me, 13397 Marseille Cedex 20, France. |
| |
| Abstract: | A distinct step in the isotherm occurs during the adsorption of CO2 on MIL-53 at 304 K. Such behavior is neither observed during the adsorption of CH4 on MIL-53 nor during the adsorption on the isostructural MIL-47. This phenomenon seems to be due to a different mechanism than that of previous adsorption steps on MOF samples. It is suggested that a breathing behavior is induced in MIL-53 during CO2 adsorption. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
