Thin-layer chromatography of inorganic ions on polyethyleneimine cellulose in sulfuric acid and acid-ammonium sulfate media |
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Authors: | T. Shimizu E. Uehara M. Ohtani |
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Affiliation: | (1) Department of Chemistry, Faculty of Education, Gunma University, Aramaki, 371 Maebashi, Japan |
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Abstract: | Summary The thin-layer chromatographic behavior of 49 inorganic ions on polyethyleneimine (PEI) cellulose, a weakly basic anion-exchanger, has been systematically studied in sulfuric acid and ammonium sulfate media (both 0.01–1.0 moldm−3). The sorption on the cellulose decreases with increasing concentration of the acid or sulfate for most of the ions and to a lesser extent for Hg(II), Bi(III), Th(IV), Nb(V), and U(VI). The Rf values of Pd(II), Ru(III), Au(III), Pt(IV), and Ta(V) are extremely low in both systems. Ba(II), Pb(II), Sb(III), Mo(VI), and W(VI) are also strongly retained on the layer. Oxy-anions such as As(III) and Se(VI) are not adsorbed on the cellulose to any great extent, but Re(VII) distributes on the plate with a Rf value of about 0.5. The characteristic retention on PEI-cellulose layer of several polyvalent ions, which form anionic sulfato complexes, can be observed in ammonium sulfate media. Possibilities for separations of analytical interest are also demonstrated in both systems. |
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Keywords: | Thin-layer chromatography Polyethyleneimine (PEI) cellulose Inorganic ions Sulfuric aicd-sulfate media |
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