Organocatalytic trifluoromethylation of imines using phase-transfer catalysis with phenoxides. A general platform for catalytic additions of organosilanes to imines |
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| Authors: | Bernardi Luca Indrigo Eugenio Pollicino Salvatore Ricci Alfredo |
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| Institution: | Department of Organic Chemistry A. Mangini, University of Bologna, V. Risorgimento 4, 40136 Bologna, Italy. luca.bernardi2@.unibo.it |
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| Abstract: | A new approach to additions of silicon nucleophiles to imines was developed. The method is based on the phase-transfer of phenoxides by ammonium catalysts, overcoming the inability of amide adducts in promoting the reactions. |
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