A reassignment of the vibrational fundamentals of sulfuryl chloride fluoride |
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| Affiliation: | 1. Swinburne University of Technology, Hawthorn, Victoria, Australia;2. Zhejiang Industry & Trade Vocational College, Wenzhou, Zhejiang, China;3. Jilin University, Changchun, Jilin, China;4. RMIT University, Melbourne, Victoria, Australia;5. Stony Brook University, Stony Brook, NY, United States |
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| Abstract: | Low temperature Raman spectroscopy has led to a significant revision in the assignment of the vibrational fundamentals of sulfuryl chloride fluoride (SO2FCl). The fundamentals in cm−1 are: (a′) 1230, 826, 632, 503, 422, 295; (a″) 1469, 476, 303. All are from gas-phase i.r. spectra except 295 cm−1, which is from the liquid-phase Raman spectrum. The revised assignments are consistent with the predictions of Pfeiffer's normal coordinate calculations [Z. phys. chem., Leipzig 240, 380 (1969)]. |
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