Structure and reactions of benzo-4-diphenylphosphino-2-phenyl-1,3,2-dioxaborinane |
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Authors: | G. N. Nikonov A. S. Balueva A. A. Karasik I. A. Litvinov S. R. Prokhorova O. N. Kataeva |
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Abstract: | The crystal structure of 5,6-benzo-4-diphenylphosphino-2-phenyl-1,3,2-dioxaborinane 1 indicates the occurrence of an interaction between the π-systems of the 1,3,2-dioxaborinane ring and the appropriate phenyl group of the diphenylphosphino group. Complexes of compound 1 with PtCl2, PdCl2, and Cul were synthesized. Compound 1 and its complexes are readily hydrolyzed in solution to give diphenylphosphine and its corresponding complexes (NMR). |
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