2-Phosphinophenolate complexes: formation and crystal structure of a novel trinuclear mu-O nickel(II)-tris(P(intersection)O-chelate) |
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| Authors: | Heinicke Joachim Peulecke Normen Karaghiosoff Konstantin Mayer Peter |
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| Institution: | Institut für Chemie und Biochemie, Ernst-Moritz-Arndt-Universit?t Greifswald, D-17487 Greifswald, Germany. heinicke@uni-greifswald.de |
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| Abstract: | A novel linear trinuclear mu-O-bridging 2-phosphinophenolate nickel(II) complex with fac-tris(P(intersection)O- chelates) in the terminal positions and the three oxygen atoms each facing the central nickel(II) cation was synthesized and structurally characterized by X-ray crystallography. To the best of our knowledge, this is the first example of an octahedral Ni(II) tris(P(intersection)O- chelate). |
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