Abstract: | In the ternary title compound, catena‐polysilver(I)‐μ‐ethylenediamine‐κ2N:N′] 3‐nitrobenzoate monohydrate], {Ag(C2H8N2)](C7H4NO4)·H2O}n, the Ag atom is bicoordinated in a linear configuration by two different N atoms from two symmetry‐related ethylenediamine ligands, thus giving linear polymeric chains with an –Ag—N—C—C—N–]n backbone running parallel to the a axis. In the crystal packing, these linear chains are interconnected by N—H?O and O—H?O hydrogen bonds to form layers parallel to the ab plane. |