Tripotassium tris(oxalato‐κ2O,O′)aluminate bis(hydrogen peroxide) hydrate,the first example of a cyclic hydrogen‐bonded H2O2 dimer |
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Authors: | Sunil Chohan Robin G Pritchard |
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Abstract: | In addition to associating into cyclic hydrogen‐bonded dimers O⋯O = 2.663 (1) and 2.914 (1) Å], each hydrogen peroxide molecule in the title structure, K3Al(C2O4)3]·1.75H2O2·0.25H2O, hydrogen bonds to a neighbouring oxalate ligand O⋯O = 2.700 (1) and 2.730 (1) Å] and coordinates to two K+ ions K⋯O = 2.6620 (9)–2.8380 (7) Å]. |
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