Tetraaquacobalt(II) bis[vanadyl(IV) phosphate], [Co(H2O)4][VO(PO4)]2 |
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Authors: | Bi‐Zhou Lin Xiao‐Ke Pei Pei‐De Liu |
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Abstract: | The structure of Co(H2O)4]VO(PO4)]2 is composed of VO(PO4)] layers and interlayer tetrahydrated Co2+ ions. Alternating VO5 square pyramids and PO4 tetrahedra share O‐atom vertices, thus forming the vanadyl phosphate layers. Two vanadyl oxo groups from neighbouring layers are coordinated to each Co atom in a trans fashion, with Co—O distances of 2.157 (4) Å, thus generating a three‐dimensional framework structure. |
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