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Tetra­aqua­cobalt(II) bis­[vanadyl(IV) phosphate], [Co(H2O)4][VO(PO4)]2
Authors:Bi‐Zhou Lin  Xiao‐Ke Pei  Pei‐De Liu
Abstract:The structure of Co(H2O)4]VO(PO4)]2 is composed of VO(PO4)] layers and interlayer tetrahydrated Co2+ ions. Alternating VO5 square pyramids and PO4 tetrahedra share O‐atom vertices, thus forming the vanadyl phosphate layers. Two vanadyl oxo groups from neighbouring layers are coordinated to each Co atom in a trans fashion, with Co—O distances of 2.157 (4) Å, thus generating a three‐dimensional framework structure.
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