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[N,N′‐Bis(3‐aminopropyl)ethylenediamine‐κ4N,N′,N′′,N′′′](trithiocyanurato‐κ2N,S)zinc(II) ethanol solvate
Authors:Jaromír Marek  Pavel Kopel  Zden k Trvní ek
Abstract:In the crystal structure of the title compound, N,N′‐bis(3‐­amino­propyl)­ethyl­enedi­amine‐κ4N,N′,N′′,N′′′]1,3,5‐triazine‐2,4,6(1H,3H,5H)‐tri­thionato(2?)‐κ2N,S]­zinc(II) ethanol sol­vate, Zn(C8H22N4)2(C3HN3S3)]·C2H6O, the ZnII atom is octa­hedrally coordinated by four N atoms Zn—N = 2.104 (2)–2.203 (2) Å] of a tetradentate N‐donor N,N′‐bis(3‐­amino­propyl)­ethyl­enedi­amine (bapen) ligand and by two S and N atoms Zn—S = 2.5700 (7) Å and Zn—N = 2.313 (2) Å] of a tri­thio­cyanurate(2?) (ttcH2?) dianion bonded as a bidentate ligand in a cis configuration. The crystal structure of the compound is stabilized by a network of hydrogen bonds.
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