Abstract: | The title compound, C14H26N8O2, belongs to a class of retropeptides with an oxalamide unit (–NH–CO–CO–NH–), and is a precursor for the synthesis of an amine‐terminal gelator. The compound is a good synthon for one‐dimensional hydrogen bonding. The crystal structure reveals a hydrogen‐bonded cyclic dimer with unusual twofold rotation symmetry. |